Vacuum Air-gapped Membrane Distillation - base model (VAGMD-base)

This Vacuum Air-gapped Membrane Distillation - base (VAGMD-base) unit model
  • supports steady-state only

  • represents a single module from Aquastill

  • is a surrogate model

  • is verified against the operation data in Plataforma Solar de Almeria (PSA)

Degrees of Freedom

The VAGMD model has at least 6 degrees of freedom that should be fixed for the unit to be fully specified.

Variables

Variable name

Symbol

Valid range

Unit

Feed salinity

feed_props.conc_mass_phase_comp[‘Liq’, ‘TDS’]

\(X_{f}\)

35 - 292

\(\text{g/}\text{L}\)

Feed temperature

feed_props.temperature

\(T_{f}\)

20 - 30

\(^o\text{C}\)

Feed flow rate

steam_props.temperature

\(FFR\)

400 - 1100

\(\text{L}/\text{h}\)

Condenser inlet temperature

condenser_in_props.temperature

\(TCI\)

20 - 30

\(^o\text{C}\)

Evaporator inlet temperature

evaporator_in_props.temperature

\(TEI\)

60 - 80

\(^o\text{C}\)

Cooling water inlet temperature

cooling_in_props.temperature

\(T_{cooling,in}\)

20 - 30

\(^o\text{C}\)

The cooling water inlet temperature is not required when cooling system type is set to “closed”. See details in Design Configurations below.

Design configurations

Different operation mode will be selected in the model by specifying the following configuration key-value pairs:

module_type: Selection between two available Aquastill MD modules: AS7C1.5L or AS26C7.2L. The first one has a length of 1.5 \(m\) and an area of 7 \(m^2\), while the latter has a length of 7.2 \(m\) with an area of 25.92 \(m^2\).

cooling_system_type: Selection between closed or open. In the closed cooling circuit, the condenser inlet temperature (TCI) is forced to be constant and the cooling water temperature (\(T_{cooling,in}\)) can be adjusted. In the open cooling circuit, the cooling process is available at a constant water temperature (\(T_{cooling,in}\)) and condenser inlet temperature (TCI) varies.

high_brine_salinity: True or False, indicates whether the brine salinity is high (> 175.3 g/L) or not. It can be inferred given a feed salinity.

Different surrogate equations will be applied based on the module_type and high_brine_salinity specifications.

Model Structure

This VAGMD model consists of 11 StateBlocks and 2 Ports as in parenthesis below:

  • Feed flow (feed)

  • Permeate flow

  • Evaporator inlet flow

  • Evaporator outlet flow (brine)

  • Condenser inlet flow

  • Condenser outlet flow

  • Cooling inlet flow

  • Cooling outlet flow

  • Average status in the cooler

  • Average status in the heater

  • Average status in the condenser

Sets

Description

Symbol

Indices

Time

\(t\)

[0]

Phases

\(p\)

[‘Liq’]

Components

\(j\)

[‘H2O’, ‘TDS’]

Variables

The system configuration variables should be fixed at the default values, which are corresponded to a single Aquastill module:

Description

Symbol

Variable Name

Value

Units

Pump efficiency

\(\eta\)

pump_efficiency

0.6

\(\text{dimensionless}\)

Heat exchanger area

\(A_{exchanger}\)

heat_exchanger_area

1.34

\(\text{m}^2\)

Cooling water volumetric flow rate

\(v_{cooling}\)

cooling_flow_rate

1265

\(\text{L}/\text{h}\)

Overall heat transfer coefficient

\(U\)

thermal_heat_transfer_coeff

3168

\(\text{W}/(\text{m}^2 \text{K})\)

The following performance variables are derived from the surrogate equations:

Description

Symbol

Variable Name

Units

Permeate flux

\(PFlux\)

permeate_flux

\(\text{L} / (\text{m}^2\text{/h})\)

Pressure drop of the feed flow

\(\Delta P_{feed}\)

feed_flow_pressure_drop

\(Pa\)

Pressure drop of the feed flow

\(\Delta P_{cool}\)

cooling_flow_pressure_drop

\(Pa\)

Evaporator outlet temperature

\(TEO\)

evaporator_out_props.temperature

\(K\)

Condenser outlet temperature

\(TCO\)

condenser_out_props.temperature

\(K\)

Equations

Description

Equation

Permeate flow rate

\(v_{permeate} = PFlux \times A\)

Brine volumetric flow rate

\(v_{brine} = v_{feed} - v_{permeate}\)

Brine salinity

\(X_{brine} = \frac{v_{feed} X_{feed}}{v_{brine}}\)

Cooling power requirement

\(P_{cooling} = R_{hot} * (T_{f} - TCI)\)

Thermal resistance on the hot side

\(R_{hot} = v_{cooling,in} \times \rho_{heater} \times C_{p, heater}\)

Thermal resistance on the cold side

\(R_{cold} = v_{cooling,in} \times \rho_{cooler} \times C_{p, cooler}\)

Number of transfer units

\(NTU = \frac{\eta A_{exchanger}}{R_{hot}}\)

Effectiveness of the heat exchanger

\(\epsilon = \frac{1 - e^{1-NTU\frac{R_{hot}}{R_{cold}}}}{1-\frac{R_{hot}}{R_{cold}}e^(1-NTC\frac{R_{hot}}{R_{cold}})}\)

Cooling water properties will be calculated based on the cooling system type:

Description

Equation

Inlet cooling watet temperature

\(TCI = T_{feed} - \frac{P_{cooling}}{\epsilon R_{hot}}\)

Outlet cooling water temperature (closed)

\(TCO = TCI + \frac{R_{hot} (T_{feed} - TCI)}{R_{cold}}\)

Outlet cooling water temperature (open)

\(TCO = TCI + \frac{P_{cooling}}{R_{cold}}\)

Surrogate equations and the corresponding coefficients for different number of effects can be found in the unit model class.

References

[1] J.A. Andres-Manas, I. Requena, G. Zaragoza, Characterization of the use of vacuum enhancement in commercial pilot-scale air gap membrane distillation modules with different designs, Desalination 528 (2022), 115490, https://doi.org/10.1016/j.desal.2021.115490.

[2] J.A. Andres-Manas, A. Ruiz-Aguirre, F.G. Acien, G. Zaragoza, Performance increase of membrane distillation pilot scale modules operating in vacuum-enhanced airgap configuration, Desalination 475 (2020), 114202, https://doi.org/10.1016/j.desal.2019.114202.